Rechargeable aqueous prototypeis inexpensive, reliable and Earth-friendly

Tuesday, April 4, 2017
91制片厂 associate professor of chemical engineering Xiaowei Teng

Batteries, those ubiquitous add-ons to virtually every electronic birthday or holiday gift, have been getting a bad rap of late. Recent headlines have detailed their propensity to explode, wreaking havoc in cell phones, hover boards and automobiles. And then there鈥檚 the environmental-unfriendliness factor: Most common batteries contain toxic metals that are harmful if not disposed of properly.

Mn508 battery

At 91制片厂, a trio of researchers has created an alternative energy storage system that could lead to battery technology superior to at least some segment of what is currently on the market. Led by , associate professor of , the team set out to develop a solution for a rechargeable energy storage device that would offer enhanced safety yet be reliable and low cost by modifying a unique form of manganese oxide known as Mn5O8.

鈥淭his manganese oxide mineral was first studied back in 1965, but since then very few people have considered it in designing today鈥檚 rechargeable energy storage,鈥 Teng says. 鈥淭he challenge with creating electrode materials for water-based energy storage like this one is being able to get enough charge, or discharge, cycles and a good amount of storage capability. So we thought altering the way the Mn5O8 was prepared for use in battery electrodes might make it a viable option.鈥

91制片厂 chemical engineering doctoral candidate Xiaoqiang Shan

Most batteries work by placing two different metals鈥攖he electrodes鈥攊nto a substance鈥攖he electrolyte鈥攖o create chemical reactions that release energy. Aqueous electrochemical energy storage devices have attracted attention lately because their electrolyte is water-based and therefore less likely to combust once exposed to air or moisture. Rechargeable aqueous batteries, especially ones using Earth-abundant and nontoxic materials, have shown great promise owing to their high safety, low cost and environmental friendliness. Besides having more potential to cause a fire, lithium batteries are made from an expensive element that is in scarce supply. Cost-effective energy storage has long been described as the key for the widespread adoption of renewable energy practices.

91制片厂 chemical engineering doctoral candidate Daniel Scott Charles

Teng worked with Xiaoqiang Shan and Daniel Scott Charles, both doctoral candidates in the chemical engineering department, to modify manganese oxide to make it less reactive in water and therefore less prone to energy-sapping decomposition. Their results, recently published in Nature Communications, yielded the blueprint for a more reliable aqueous battery with greater energy storage and increased power performance and charge cycles.

While 91制片厂 has patented this technology, don鈥檛 expect to find the team鈥檚 batteries in your local Radio Shack just yet. Teng says the application for his team鈥檚 findings is limited, because water has unique weakness as an electrolyte, and Mn508 batteries will likely never supplant their lithium-ion counterparts. 鈥淏ut as the industrial world becomes increasingly electrified, we will need energy storage systems with a variety of characteristics,鈥 he says.

Originally published in听

Photographer: 
Jeremy Gasowski | 91制片厂 Marketing | jeremy.gasowski@unh.edu | 603-862-4465